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BS EN 71-5:2015

BS EN 71-5:2015

$215.11

Safety of toys – Chemical toys (sets) other than experimental sets

Published By Publication Date Number of Pages
BSI 2015 84
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This European Standard specifies requirements and test methods for the substances and materials used in chemical toys (sets) other than experimental sets. These substances and mixtures are:

  • those classified as dangerous by the EU-legislation applying to dangerous substances and dangerous mixtures [5];

  • substances and mixtures which in excessive amounts could harm the health of the children using them and which are not classified as dangerous by the above mentioned legislation; and

  • any other chemical substance(s) and mixture(s) delivered with the chemical toy.

NOTE

The terms “substance” and “mixture” are defined in the REACH regulation No. (EC)1907/2006 and in the CLP regulation (EC) No. 1272/2008.

Additionally, requirements are specified for markings, warnings, safety rules, contents list, instructions for use and first aid information.

This Part of EN 71 applies to:

  • plaster of Paris (gypsum) moulding sets;

  • oven-hardening plasticised PVC modelling clay sets;

  • polystyrene granules sets;

  • embedding sets;

  • adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents), supplied or recommended in model sets.

PDF Catalog

PDF Pages PDF Title
10 1 Scope
2 Normative references
11 3 Terms and definitions
12 4 Plaster of Paris (gypsum) moulding sets
4.1 Marking
4.2 First aid information
4.3 Safety rules
13 5 Oven-hardening plasticised PVC modelling clay sets
5.1 Chemical substances
5.2 Marking
5.3 First aid information
14 5.4 Safety rules
6 Moulding sets
6.1 Polystyrene granules sets
6.1.1 Chemical substances
6.1.2 Marking
6.1.3 First aid information
15 6.1.4 Safety rules
6.2 Embedding sets
6.2.1 General
6.2.2 Packaging
6.2.3 Marking
6.2.4 First aid information
6.2.5 Safety rules
16 7 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets
7.1 General
7.2 Adhesives
7.2.1 Water-based adhesives
7.2.1.1 General
7.2.1.2 Liquid adhesives for paper and wood
18 7.2.1.3 Adhesive sticks and pastes for paper
19 7.2.2 Solvent-based adhesives
7.2.2.1 General
7.2.2.2 Multi-purpose adhesives
7.2.2.3 Contact adhesives
20 7.2.2.4 Special adhesives
21 7.2.2.5 Packaging
7.2.2.6 Marking
7.2.2.7 First aid information
22 7.2.2.8 Safety rules
7.3 Water-based paints or lacquers
7.3.1 General
7.3.2 Packaging
7.3.3 Marking
23 7.3.4 First aid information
7.3.5 Safety rules
7.4 Solvent-based paints, lacquers, thinners and cleaning solvents
7.4.1 General
24 7.4.2 Packaging
7.4.3 Marking
7.4.4 First aid information
25 7.4.5 Safety rules
8 Marking
8.1 General
8.2 Marking of the primary packaging
8.2.1 General
8.2.2 Manufacturer’s identification
8.2.3 Warning phrases
26 8.3 Marking of individual containers and any packagings
9 Instructions for use
9.1 General
9.2 Contents list
9.3 Advice for adult supervision
27 9.4 Safety rules
9.5 Instructions for carrying out the activities
9.6 Spills and disposal of chemicals
28 10 Test methods
10.1 General
10.2 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets
10.2.1 Principle
10.2.2 Standards and reagents
10.2.2.1 Standards
29 10.2.2.2 Reagents
10.2.3 Apparatus
30 10.2.4 Preparation of standard solutions
10.2.4.1 Stock solutions
31 10.2.4.2 Calibration solutions
10.2.4.3 Stability of standard solutions
10.2.5 Sampling
32 10.2.6 Sample preparation
10.2.7 Procedure
10.2.7.1 General
10.2.7.2 Extraction of citric acid esters and alkylsulfonic acid esters
10.2.7.3 Extraction of adipic acid polyesters
10.2.7.4 Evaporation of the solvent and weighing
33 10.2.7.5 Blank determination
10.2.7.6 GC-MSD determination of citric acid esters and alkylsulfonic acid esters
10.2.7.7 ATR-FT-IR identification of adipic acid polyesters
10.2.8 Evaluation of results
10.2.8.1 Calculation of solvent-extractable content containing plasticisers
34 10.2.8.2 Calculation and identification of plasticiser content by GC-MS analysis
35 10.2.9 Test report
10.3 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and polystyrene granules sets
10.3.1 Principle
36 10.3.2 Standards and reagents
10.3.3 Apparatus
10.3.3.1 Gas chromatograph with mass spectrometer detector (GC-MS)
37 10.3.3.2 Headspace analysis conditions
10.3.3.3 Other laboratory equipment
38 10.3.4 Preparation of standard solutions
10.3.5 Sampling
10.3.6 Sample preparation
10.3.7 Procedure
10.3.8 Evaluation of results
39 10.3.9 Test report
10.3.10 Critical control points
10.4 Determination of styrene content in polystyrene granules
10.4.1 Principle
10.4.2 Standards and reagents
10.4.2.1 Standards
40 10.4.2.2 Reagents
10.4.3 Apparatus
41 10.4.4 Preparation of the standard solutions
10.4.5 Sampling
10.4.6 Sample preparation
10.4.7 Procedure
10.4.8 Evaluation of results
10.4.9 Test report
42 10.5 Determination of organic solvents
10.5.1 General
44 10.5.2 Principle
45 10.5.3 Standards and reagents
10.5.3.1 Standards
46 10.5.3.2 Reagents
10.5.4 Apparatus
48 10.5.5 Preparation of the standard solutions
10.5.5.1 Stock solutions for the identification and determination of solvents using HS-GC-FID
49 10.5.5.2 Stock solutions for the identification and determination of solvents using GC-MS
50 10.5.5.3 Stock solution for the identification and determination of propane-1,2-diol
10.5.5.4 Calibration solutions
55 10.5.6 Sampling
10.5.7 Sample preparation
10.5.7.1 General
56 10.5.7.2 Sample preparation for identification and determination of solvents by HS-GC-FID
10.5.7.3 Sample preparation for identification of solvents by GC-MS
10.5.7.4 Sample preparation for determination of certain solvents by GC-MS
57 10.5.7.5 Sample preparation for determination of propane-1,2-diol using GC-FID
10.5.8 Procedure
10.5.8.1 Identification of solvents using HS-GC-FID
60 10.5.8.2 Identification of solvents using GC-MS
61 10.5.8.3 Determination of solvent content by HS-GC-FID
62 10.5.8.4 Determination of solvent content using GC-MS
10.5.8.5 Determination of propane-1,2-diol by GC-FID
10.5.8.6 Blank determination
10.5.9 Evaluation of results
10.5.9.1 Calculation of solvent content by HS-GC-FID
63 10.5.9.2 Calculation of solvent content by GC-MS or GC-FID
10.5.10 Test report
10.6 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints or lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints or lacquers
10.6.1 Principle
64 10.6.2 Determination of total extract
10.6.2.1 Standards and reagents
10.6.2.2 Apparatus
10.6.2.3 Sampling
10.6.2.4 Sample preparation
65 10.6.2.5 Procedure
10.6.2.6 Evaluation of results
10.6.3 Identification of nitrocellulose
10.6.3.1 Principle
10.6.3.2 Reagents
10.6.3.3 Apparatus
66 10.6.3.4 Sampling
10.6.3.5 Sample preparation
10.6.3.6 Procedure
10.6.3.7 Evaluation of results
67 10.6.4 Determination of plasticisers
10.6.4.1 Principle
10.6.4.2 Standards and reagents
10.6.4.3 Apparatus
10.6.4.4 Preparation of the standard solution
10.6.4.5 Procedure
10.6.4.6 Evaluation of results
10.6.5 Determination of film-forming agents
10.6.5.1 Principle
68 10.6.5.2 Standards and reagents
10.6.5.3 Apparatus
71 10.6.5.4 Preparation of standard solutions
72 10.6.5.5 Sampling
10.6.5.6 Procedure
10.6.5.7 Evaluation of results
73 10.6.6 Determination of the modifiers
10.6.7 Test report

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BS EN 71-5:2015
$215.11